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1

Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates

Nie, Jing, Guo, Hong-Chao, Cahard, Dominique, Ma, Jun-An

Journal:

Chemical Reviews

Year:

2011

Language:

english

File:

PDF, 2.90 MB

english, 2011

2

Towards Perfect Catalytic Asymmetric Synthesis: Dual Activation of the Electrophile and the Nucleophile

Jun-An Ma, Dominique Cahard

Journal:

Angewandte Chemie International Edition

Year:

2004

Language:

english

File:

PDF, 973 KB

english, 2004

3

Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp 3 )–H Bonds

Xiong, Heng-Ying, Besset, Tatiana, Cahard, Dominique, Pannecoucke, Xavier

Journal:

Journal of Organic Chemistry

Year:

2015

Language:

english

File:

PDF, 920 KB

english, 2015

4

Trifluoromethyl Sulfoxides from Allylic Alcohols and Electrophilic SCF 3 Donor by [2,3]-Sigmatropic Rearrangement

Maeno, Mayaka, Shibata, Norio, Cahard, Dominique

Journal:

Organic Letters

Year:

2015

Language:

english

File:

PDF, 711 KB

english, 2015

5

Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo(difluoro)acetate: A Straightforward Access to Highly Valuable Difluoromethylated Alkenes

Belhomme, Marie-Charlotte, Dru, Delphine, Xiong, Heng-Ying, Cahard, Dominique, Besset, Tatiana, Poisson, Thomas, Pannecoucke, Xavier

Journal:

Year:

2014

Language:

english

File:

PDF, 301 KB

english, 2014

6

Enantioselective Base-Free Electrophilic Amination of Benzofuran-2(3H)-ones: Catalysis by Binol-Derived P-Spiro Quaternary Phosphonium Salts

Chuan-Le Zhu, Fa-Guang Zhang, Wei Meng, Jing Nie, Dr. Dominique Cahard, Prof. Jun-An Ma

Journal:

Angewandte Chemie International Edition

Year:

2011

Language:

english

File:

PDF, 477 KB

english, 2011

7

Ionic Liquids and Chirality: Opportunities and Challenges

Christine Baudequin, Jerome Baudoux, Jocelyne Levillain, Dominique Cahard, Annie-Claude Gaumont, Jean-Christophe Plaquevent

Journal:

Year:

2004

File:

PDF, 68 KB

2004

8

Synthesis from Other Ketones

J.-C. Plaquevent, D. Cahard, F. Guillen

Journal:

Year:

2005

File:

PDF, 8 KB

2005

9

A new tetrasubstituted α-fluoro cyclohexanone bearing a fluoroisopropyl group at C5

Arlette Solladié-Cavallo, Khalid Azyat, Loïc Jierry, Dominique Cahard

Journal:

Journal of Fluorine Chemistry

Year:

2006

Language:

english

File:

PDF, 428 KB

english, 2006

10

Strategies for nucleophilic, electrophilic, and radical trifluoromethylations

Jun-An Ma, Dominique Cahard

Journal:

Journal of Fluorine Chemistry

Year:

2007

Language:

english

File:

PDF, 2.97 MB

english, 2007

11

Enantioselective electrophilic fluorination: a study of the fluorine-transfer from achiral N–F reagents to cinchona alkaloids

Christine Baudequin, Jean-François Loubassou, Jean-Christophe Plaquevent, Dominique Cahard

Journal:

Journal of Fluorine Chemistry

Year:

2003

Language:

english

File:

PDF, 127 KB

english, 2003

12

Screening of chiral catalysts for enantioselective electrophilic fluorination of β-ketoesters

Jun-An Ma, Dominique Cahard

Journal:

Journal of Fluorine Chemistry

Year:

2004

Language:

english

File:

PDF, 114 KB

english, 2004

13

Diastereoselective synthesis of trans-trifluoromethyl-β-lactams and α-alkyl-β-trifluoromethyl-β-amino esters

Vitaliy Petrik, Gerd-Volker Röschenthaler, Dominique Cahard

Journal:

Year:

2011

Language:

english

File:

PDF, 467 KB

english, 2011

14

Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

Cahard, Dominique, Ma, Jun-An

Journal:

Chemical Reviews

Year:

2008

Language:

english

File:

PDF, 5.18 MB

english, 2008

15

Die Trifluormethylierung von Arenen und Heteroarenen

Dr. Tatiana Besset, Dr. Cédric Schneider, Dr. Dominique Cahard

Journal:

Angewandte Chemie

Year:

2012

Language:

german

File:

PDF, 416 KB

german, 2012

16

Decarboxylative Allylation of Trifluoroethyl Sulfones and Approach to Difluoromethyl Compounds

Shibata, Norio, Fukushi, Kazunobu, Furukawa, Tatsuya, Suzuki, Satoru, Tokunaga, Etsuko, Cahard, Dominique

Journal:

Organic Letters

Year:

2012

Language:

english

File:

PDF, 278 KB

english, 2012

17

P-Spiro phosphonium salts catalyzed asymmetric fluorination of 3-substituted benzofuran-2(3H)-ones

Zhu, Chuan-Le, Fu, Xiao-Yun, Wei, Ai-Jia, Cahard, Dominique, Ma, Jun-An

Journal:

Journal of Fluorine Chemistry

Year:

2013

Language:

english

File:

PDF, 996 KB

english, 2013

18

Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

Ma, Jun-An, Cahard, Dominique

Journal:

Chemical Reviews

Year:

2004

Language:

english

File:

PDF, 931 KB

english, 2004

19

Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization

Bizet, Vincent, Pannecoucke, Xavier, Renaud, Jean-Luc, Cahard, Dominique

Journal:

Journal of Fluorine Chemistry

Year:

2013

Language:

english

File:

PDF, 406 KB

english, 2013

20

Chiral N -Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination

Zhu, Chuan-Le, Maeno, Mayaka, Zhang, Fa-Guang, Shigehiro, Taiki, Kagawa, Takumi, Kawada, Kosuke, Shibata, Norio, Ma, Jun-An, Cahard, Dominique

Journal:

European Journal of Organic Chemistry

Year:

2013

Language:

english

File:

PDF, 431 KB

english, 2013

21

Regio- and Diastereoselective Cu-Mediated Trifluoromethylation of Functionalized Alkenes

Besset, Tatiana, Cahard, Dominique, Pannecoucke, Xavier

Journal:

Journal of Organic Chemistry

Year:

2014

Language:

english

File:

PDF, 511 KB

english, 2014

22

Synthesis, Anti-Human Immunodeficiency Virus Activity and Esterase Lability of Some Novel Carboxylic Ester-Modified Phosphoramidate Derivatives of Stavudine (d4T)

McGuigan, C., Sutton, P., Cahard, D., Turner, K., O'Leary, G., Wang, Y., Gumbleton, M., De Clercq, E., Balzarini, J.

Journal:

Antiviral Chemistry & Chemotherapy

Year:

1998

Language:

english

File:

PDF, 178 KB

english, 1998

23

Regio- and Stereocontrolled Nucleophilic Trifluoromethylthiolation of Morita–Baylis–Hillman Carbonates

Dai, Xiaoyang, Cahard, Dominique

Journal:

Year:

2014

Language:

english

File:

PDF, 197 KB

english, 2014

24

Novel Use of CF 3 SO 2 Cl for the Metal-Free Electrophilic Trifluoromethylthiolation

Chachignon, Hélène, Maeno, Mayaka, Kondo, Hiroya, Shibata, Norio, Cahard, Dominique

Journal:

Organic Letters

Year:

2016

Language:

english

File:

PDF, 869 KB

english, 2016

25

ChemInform Abstract: Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination.

Zhu, Chuan-Le, Maeno, Mayaka, Zhang, Fa-Guang, Shigehiro, Taiki, Kagawa, Takumi, Kawada, Kosuke, Shibata, Norio, Ma, Jun-An, Cahard, Dominique

Journal:

Year:

2014

File:

PDF, 33 KB

2014

26

State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents

Chachignon, Hélène, Cahard, Dominique

Journal:

Chinese Journal of Chemistry

Year:

2016

Language:

english

File:

PDF, 555 KB

english, 2016

27

Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)-H Bonds at Room Temperature

Xiong, Heng-Ying, Cahard, Dominique, Pannecoucke, Xavier, Besset, Tatiana

Journal:

European Journal of Organic Chemistry

Year:

2016

Language:

english

File:

PDF, 1.01 MB

english, 2016

28

Interrupted reduction of CF3SO2Cl using tricyclohexylphosphine allows for electrophilic trifluoromethylsulfinylation

Chachignon, Hélène, Cahard, Dominique

Journal:

Journal of Fluorine Chemistry

Year:

2016

Language:

english

File:

PDF, 665 KB

english, 2016

29

Characterization of the activation pathway of phosphoramidate triester prodrugs of stavudine and zidovudine.

Saboulard, Didier, Naesens, Lieve, Cahard, Dominique, Salgado, Antonio, Pathirana, Ranjith, Velazquez, Sonsoles, McGuigan, Christopher, {De Clercq}, Erik, Balzarini, Jan

Journal:

Molecular Pharmacology

Year:

1999

Language:

english

File:

PDF, 212 KB

english, 1999

30

Nucleophilic Trifluoromethylthiolation of Cyclic Sulfamidates: Access to Chiral β- and γ-SCF 3 Amines and α-Amino Esters

Zeng, Jun-Liang, Chachignon, Hélène, Ma, Jun-An, Cahard, Dominique

Journal:

Organic Letters

Year:

2017

Language:

english

File:

PDF, 913 KB

english, 2017

31

Mechanistic Insights into the Decarboxylative Electrophilic Trifluoromethylthiolation of β-Ketocarboxylic Acids

Guyon, Hélène, Chachignon, Hélène, Tognetti, Vincent, Joubert, Laurent, Cahard, Dominique

Journal:

European Journal of Organic Chemistry

Year:

2018

Language:

english

File:

PDF, 1.82 MB

english, 2018

32

Advances in Asymmetric Di-and Trifluoromethylthiolation & Di-and Trifluoromethoxylation Reactions

Cahard, Dominique, Chachignon, Hélène, Hardy, Melissa A

Journal:

Asian Journal of Organic Chemistry

Year:

2019

Language:

english

File:

PDF, 1.69 MB

english, 2019

33

Regioselectivity Issues in the Addition of Grignard Reagents to Trifluoromethylated α-Bromoenones

Romanov, Alexey R., Cahard, Dominique, Rulev, Alexander

Journal:

European Journal of Organic Chemistry

Year:

2019

Language:

english

File:

PDF, 1.09 MB

english, 2019

34

Alkoxide-Mediated Preparation of Enolates from Silyl Enol Ethers and Enol Acetates − From Discovery to Synthetic Applications

Dominique Cahard, Pierre Duhamel

Journal:

European Journal of Organic Chemistry

Year:

2001

Language:

english

File:

PDF, 432 KB

english, 2001

35

Elektrophile Fluorierung mit Cinchonaalkaloiden: hoch enantioselektive Synthese von α-Fluor-α-phenylglycin-Derivaten

Barbara Mohar, Jérôme Baudoux, Jean-Christophe Plaquevent, Dominique Cahard

Journal:

Angewandte Chemie

Year:

2001

Language:

german

File:

PDF, 76 KB

german, 2001

36

New Insights in the Search for Chiral Brønsted Bases

Jean-Christophe Plaquevent, Thierry Perrard, Dominique Cahard

Journal:

Chemistry - A European Journal

Year:

2002

Language:

english

File:

PDF, 209 KB

english, 2002

37

Electrophilic Fluorination Mediated by Cinchona Alkaloids: Highly Enantioselective Synthesis of α-Fluoro-α-phenylglycine Derivatives

Barbara Mohar, Jérôme Baudoux, Jean-Christophe Plaquevent, Dominique Cahard

Journal:

Angewandte Chemie International Edition

Year:

2001

Language:

english

File:

PDF, 78 KB

english, 2001

38

Construction of Trifluoromethyl-Bearing Quaternary Carbon Centers by Intramolecular Decarboxylative Allylation of α-Trifluoromethyl β-Keto Esters

Norio Shibata, Satoru Suzuki, Tatsuya Furukawa, Hiroyuki Kawai, Etsuko Tokunaga, Zhe Yuan, Dominique Cahard

Journal:

Advanced Synthesis & Catalysis

Year:

2011

Language:

english

File:

PDF, 202 KB

english, 2011

39

Hoch effiziente asymmetrische Katalyse durch doppelte Aktivierung von Nucleophil und Elektrophil

Jun-An Ma, Dominique Cahard

Journal:

Angewandte Chemie

Year:

2004

Language:

german

File:

PDF, 979 KB

german, 2004

40

Enantioselective Base-Free Electrophilic Amination of Benzofuran-2(3H)-ones: Catalysis by Binol-Derived P-Spiro Quaternary Phosphonium Salts

Chuan-Le Zhu, Fa-Guang Zhang, Wei Meng, Jing Nie, Dr. Dominique Cahard, Prof. Jun-An Ma

Journal:

Angewandte Chemie

Year:

2011

Language:

english

File:

PDF, 488 KB

english, 2011

41

ChemInform Abstract: Chirons in the 1,3-Dioxane Series: Stereospecific Cross-Coupling Reactions and Chirality Transfers.

M. AMADJI, D. CAHARD, J.-D. MORIGGI, L. TOUPET, J.-C. PLAQUEVENT

Journal:

Year:

1998

File:

PDF, 30 KB

1998

42

ChemInform Abstract: Regioselective Addition of the Prenal Potassium Dienolate onto α,β-Unsaturated Aldehydes. A Short Access to Polyenaldehydes.

D. CAHARD, J.-M. POIRIER, P. DUHAMEL

Journal:

Year:

1998

File:

PDF, 33 KB

1998

43

ChemInform Abstract: Enantioselective Dehydrohalogenation Using Chiral Alkoxides: Design of a Catalytic System Allowing Access to Axially Dissymmetric Compounds.

M. AMADJI, J. VADECARD, D. CAHARD, L. DUHAMEL, P. DUHAMEL, J.-C. PLAQUEVENT

Journal:

Year:

1998

File:

PDF, 30 KB

1998

44

ChemInform Abstract: Lactate Cannot Substitute for Alanine in D4T-Based Anti-HIV Nucleotide Prodrugs — Despite Efficient Esterase-Mediated Hydrolysis.

Christopher McGuigan, Dominique Cahard, Carlo Ballatore, Adam Siddiqui, Erik De Clercq, Jan Balzarini

Journal:

Year:

1999

File:

PDF, 28 KB

1999

45

ChemInform Abstract: Prenylation Reaction Performed with Catalytically Generated Potassium Prenal Dienolate.

Dominique Cahard, Lucette Duhamel, Sandrine Lecomte, Jean-Marie Poirier

Journal:

Year:

1999

File:

PDF, 31 KB

1999

46

ChemInform Abstract: Pyrrolidines Bearing a Quaternary α-Stereogenic Center. Part 2. Access to Proline Chimeras, Stereoselective Approach and Mechanistic Aspects.

Delphine Trancard, Jean-Baptiste Tout, Thierry Giard, Ilhame Chichaoui, Dominique Cahard, Jean-Christophe Plaquevent

Journal:

Year:

2000

File:

PDF, 33 KB

2000

47

ChemInform Abstract: A General Synthesis of (2Z)-Terpenoic Acids.

Dominique Cahard, Malika Mammeri, Jean-Marie Poirier, Lucette Duhamel

Journal:

Year:

2000

File:

PDF, 32 KB

2000

48

ChemInform Abstract: Design, Synthesis, and Evaluation of a Novel Class of Enantioselective Electrophilic Fluorinating Agents: N-Fluoro Ammonium Salts of Cinchona Alkaloids (F—CA—BF4).

Dominique Cahard, Christophe Audouard, Jean-Christophe Plaquevent, Nicolas Roques

Journal:

Year:

2001

File:

PDF, 38 KB

2001

49

ChemInform Abstract: N-Fluorocinchonidinium Tetrafluoroborate F-CD-BF4: Purification and Structure Elucidation of This Novel Enantioselective Electrophilic Fluorinating Agent.

Dominique Cahard, Christophe Audouard, Jean-Christophe Plaquevent, Loic Toupet, Nicolas Roques

Journal:

Year:

2001

File:

PDF, 28 KB

2001

50

ChemInform Abstract: New Polymer-Supported Chiral Phase-Transfer Catalysts in the Asymmetric Synthesis of α-Amino Acids: The Role of a Spacer.

Baptiste Thierry, Jean-Christophe Plaquevent, Dominique Cahard

Journal:

Year:

2001

File:

PDF, 32 KB

2001

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